Interfacial transport in porous media: Application to D.C. electrical conductivity of mortars, Journal of Applied Physics, 1995 Reference: L.M. Schwartz, E.J. Garboczi, and D.P. Bentz, Journal of Applied Physics 78, 5898-5908 (1995).
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Interfacial transport in porous media:
Application to D.C. electrical conductivity of mortars

Lawrence M. Schwartz, Edward J. Garboczi, and Dale P. Bentz
National Institute of Standards and Technology,
Building Materials Division, 226/B350, Gaithersburg, MD 20899

Abstract

A mortar is a composite of inert sand grains surrounded by a porous cement paste matrix. We investigate the electrical conductivity of model mortars that include enhanced electrical conduction in the matrix - sand grain interfacial region. The electrical conductivity is evaluated by a combination of finite element, finite difference, and random walk methods for periodic and disordered models of mortar. Since the effective conductivity within the interfacial zone is often much higher than the bulk matrix conductivity, the qualitative features of transport in these systems is often controlled by the connectivity of the interfacial zone. Special attention is thus given to the geometrical percolation of this zone. A family of effective medium approximations give a good qualitative description of the disordered model's electrical properties. A simple four parameter Pade approximant is found to successfully describe the electrical conductivity of the periodic model over the entire range of parameters studied.





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