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2.5 Calculations of the degree of cement hydration, degree of reaction of mineral admixtures, and standard deviations

The volume fraction of each phase in the sample was calculated by dividing the number of points counted for that phase by the total number of points counted. When entrapped air is present, one has to correct the total number of points by subtracting the number of points that fall into the air phase. There was very little entrapped air present in these cement paste samples, certainly much less than 1 % by volume. When calculating the degree of hydration of cement, one must also correct for the volume fraction of gypsum in the clinker. Detailed calculations are shown as follows.

Symbols: 
W/c Water-to-cement ratio
V(0)cemVolume fraction of clinker particles in cement, %
V(t)cemVolume fraction of unhydrated cement at hydration time t, %
V(0)maVolume fraction of unreacted mineral admixtures before hydration, %
V(t)maVolume fraction of unreacted mineral admixtures at hydration time t, %
VfgypVolume fraction of gypsum in the clinker, %
αcemDegree of hydration of cement paste, %
αmaDegree of reaction of mineral admixtures, %
mcemMass of cement in 100g binder, g
mmaMass of mineral admixtures in 100g binder, g;
mH2OMass of water needed for 100g binder by w/c ratio, g
ρcemSpecific gravity of cement, typically 3.2
ρmaSpecific gravity of mineral admixtures, 2.36 for fly ash; 2.87 for slag
ρH2OSpecific gravity of H2O, 1.0 at 20ºC

Next: Plain portland cement pastes Up: Experimental Procedures Previous: SEM sample preparation