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It is interesting to note the early conductivity
response of the sample to the application
of the 60 volts required by the standardized RCT.
Figure 7 is a plot of effective
specimen conductivity calculated from the
RCT current for the two specimens from Sample F
during the first 4 minutes of the RCT.
The solid lines shown are only meant to guide the reader's eyes.
The dashed lines delineate the sample conductivities using IS.
The figure shows the effects of two phenomena: a decrease in current
due to the accumulation of polarization charge, and an increase in
current due to ohmic heating.
Figure 7:
Early-time conductivity, as measured by the RCT current, taken from
Sample F.
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Using these data from Specimen F, it is difficult to distinguish the
proper time at which to measure the RCT current to ensure an accurate
estimate of
σIS.
One could argue that the proper value should be determined from an
extrapolation to zero time using the values measured at one minute and
later. Although this method would be relatively accurate for the
50 mm specimen, it would not be justifiable for the 100 mm specimen.
The estimate using
the value at t=0 seems to be a reasonable compromise. Since the values
in the figure only vary by approximately 4 percent during the first 4
minutes of the test, it would seem as though sufficiently accurate
estimates of sample conductivity could be made using the DC current
measurements at any time during the first few minutes.
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Up: Results
Previous: Total Charge