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Uniform matrix expansion

Several degradation mechanisms, including freeze-thaw, some kinds of sulfate attack, and a hypothesized mechanism for so-called delayed ettringite formation [8], involve a uniform, on average, expansion of the matrix. Let us examine what effect this scenario has on stresses and displacements. Take h=0, so that there is effectively no shell phase, and let ε1o = ε, and ε3o = 0. Combining equations (3)-(7) into three equations for the three variables α3, α1, and β1, we obtain

These equations are exact, although, to be consistent with the dilute limit hypothesis, the expressions in eq. (8) should really be expanded to O(c). Using these solutions in equations (1) and (2) shows that rr is tensile, and has its greatest value right at the matrix-aggregate interface. If the stress generated is large enough, the aggregate should break away from the matrix along the interface. The tangential stress, , is equal to rr in the aggregate, but is always compressive in the matrix, so there should be no radial cracking in the matrix. If the aggregate should break away from the matrix, then there will be a non-zero displacement of the rim of the matrix. This can be computed using the same equations, but now eq. (3) can be ignored, and eq. (5) becomes the vanishing of radial stress at the (now) free boundary at r = a. Solving for the radial displacement at r = a, we find that u(r = a) = a. Since the outer edge of the detached aggregate will have zero displacement, there will be a gap around the aggregate of width a, which is proportional to the aggregate diameter. In a real concrete with many aggregates packed closely together, as long as each aggregate breaks away from the matrix, each gap will, on the average, have a width proportional to the radius of the aggregate. If some aggregates remain attached to the cement paste matrix, the stress fields will be changed somewhat, but the overall result should still be approximately true.


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