Reference: R.T. Coverdale, E.J. Garboczi, and H.M. Jennings, Computational Materials Science 3, 465-474 (1995).
PDF version of original paper

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An Improved Model for Simulating Impedance Spectroscopy

R.T. Coverdale
Master Builders, Inc.
23700 Chagrin Boulevard
Cleveland, Ohio 44122

H.M. Jennings
Northwestern University
Depts. of Materials Science and Engineering and Civil Engineering
Evanston, IL 60208

E.J. Garboczi
National Institute of Standards and Technology
Building and Fire Research Laboratory
Building Materials Division 226/B348
Gaithersburg, MD 20899

Abstract

A numerical method for simulating the frequency-dependent impedance response of multi-phase composite materials has been developed. The algorithm takes as input 1) a digital image of a microstructure, in two or three dimensions, of any specified composite material, and 2) the frequency-dependent electrical properties of the individual phases of the composite. An impedance spectrum of any frequency range can then be computed using a conjugate gradient algorithm operating on a finite difference solution scheme of Laplace's equation. Examples are given of the impedance of analytically solvable microstructures, to validate the algorithm, and of a random system, to test the usefulness of two different effective medium theories.




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