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References

1

F.M. Lea, The Chemistry of Cement and Concrete (St. Martin's Press, New York, 1956), Chapter 1.

2

J.F. Young, A Review of the Pore Structure of Cement Paste and Concrete and Its Influence on Permeability, in Permeability of Concrete, ed. by D. Whiting and A. Walitt, ACI SP-108 (American Concrete Institute, Detroit, 1988).

3

E.J. Garboczi, Computational materials science of cement-based materials, Materials and Structures 26, 191-195 (1993).

4

H.F.W. Taylor, Cement Chemistry (Academic Press, San Diego,1990).

5

R. Maggion, PhD thesis, L'Universit D'Orleans, France 1992.

6

A.J. Allen, R.C. Oberthur, D. Pearsons, P. Schofield, and C.R. Wilding, Development of the fine porosity and gel structure of hydrating cement systems, Philosophical Magazine B 56, No. 3, pp. 263-288 (1987).

7

E.J. Garboczi, M.F. Thorpe, M. DeVries, and A.R. Day, "Universal Conductivity Curve for a Plane Containing Random Holes," Physical Review A 43, 6473-6482 (1991).

8

E.J. Garboczi, K.A. Snyder, J.F. Douglas, and M.F. Thorpe, "Geometrical percolation threshold of overlapping ellipsoids," Phys. Rev. E 52, 819-828 (1995).

9

a) J. Kertesz, J. Phys. Lett. (Paris) 42, L393 (1981), b) W.T Elam, A.R. Kerstein, and J.J. Rehr, Phys. Rev. Letts. 52, 1516 (1984), c) S.B. Lee and S. Torquato, Porosity for the penetrable-concentric-shell model of two-phase disordered media: Computer simulation results, J. Chem. Phys. 89, 3258 (1988).

10

D.P. Bentz and P.E. Stutzman, SEM Analysis and Computer Modelling of Hydration of Portland Cement Particles, in ASTM STP 1215, ed. S.M. DeHayes and D. Stark (American Society for Testing and Materials, Philadelphia, 1994), 60-73.

11

High-Performance Construction Materials and Systems: An Essential Program for America and Its Infrastructure, Technical Report 93-5011 (Civil Engineering Research Foundation, Washington, D.C., 1993).

12

D.P. Bentz, P.V. Coveney, E.J. Garboczi, M.F. Kleyn, and P.E. Stutzman, Cellular automaton simulations of cement hydration and microstructure development," Modelling and Simulation in Materials Science and Engineering 2, 783-808 (1994).

13

D.P. Bentz, and E.J. Garboczi, Guide to Using HYDRA3D: A Three-Dimensional Digital-Image-Based Cement Microstructure Model NISTIR 4746, U.S. Department of Commerce (1992). Updated version of manual and code

14

Wei-Guo Lei, Rheological studies and percolation modelling of microstructure development of fresh cement paste, Ph.D. Thesis, University of Illinois, Department of Materials Science and Engineering, 1995.

15

Y. Chen and I. Odler, On the Origin of Portland Cement Setting, Cem. Conc. Res. 22, 1130-1140 (1992).

16

ASTM C-191 (1992) Standard Test Method for Time of Setting of Hydraulic Cement by Vicat Needle, American Society for Testing of Materials, Philadelphia, Pa.

17

C.M. Sayers and R.L. Grenfell, Ultrasonic propagation through hydrating cements, Ultrasonics 31, 147-153 (1993).

18

S.P. Jiang, J.C. Mutin, and A. Nonat, Analysis of the Hydration Setting Relation: Towards a Comprehensive Approach to Cement Setting, in Proceedings of the 9th International Congress on the Chemistry of Cement, Vol. IV, 17-23, New Delhi, India.

19

D.P. Bentz and E.J. Garboczi, "Percolation of Phases in a Three-Dimensional Cement Paste Microstructural Model," Cem. and Conc. Res. 21, 325-344 (1991).

20

D.P. Bentz, E.J. Garboczi, and N.S. Martys, Application of digital-image-based models to microstructure, transport properties, and degradation of cement-based materials, in Proceedings of 1994 NATO/RILEM Workshop Computer Modelling of Microstructure and Its Potential Application to Transport Properties, edited by H.M. Jennings, pp. 167-186.

21

R.T. Coverdale, Microstructural analysis of cement paste using a computer model of impedance spectroscopy, Ph.D. thesis, Northwestern University, Department of Materials Science and Engineering, 1993.

22

C. Legrand and E. Wirquin, Effects of the initial structure of the cement paste in fresh concrete on the first developments of strength, in Proceedings of the 9th International Congress on the Chemistry of Cement, vol V, 95-99, New Delhi, India (1992).

23

S.P. Jiang, J.C. Mutin, and A. Nonat, Effect of melment superplasticizer on C3S hydration: From suspension to paste, in Proceedings of the 3rd Beijing International Symposium on Cement and Concrete, China Building Materials Academy, 126-131 (1993).

24

W.G. Lei, L.J. Struble, D.P. Bentz, E. Schlangen, and E.J. Garboczi, in preparation.

25

T.C. Powers, L.E. Copeland, and H.M. Mann, PCA Bulletin 10 (1959).

26

D.P. Bentz, unpublished.

27

B.J. Christensen, T.O. Mason, and H.M. Jennings, Influence of silica fume on the early hydration of portland cement pastes using impedance spectroscopy, Journal of the American Ceramic Society 75, 935-939 (1992).

28

R.A. Olson, B.J. Christensen, R.T. Coverdale, S.J. Ford, G.M. Moss, H.M. Jennings, T.O. Mason, and E.J. Garboczi, "Interpretation of the impedance spectroscopy of cement paste via computer modelling III: Microstructural analysis of frozen cement paste, Journal of Materials Science 30, 5078-5086 (1995).

29

P. Halamickova, R.J. Detwiler, D.P. Bentz, and E.J. Garboczi, "Water Permeability and Chloride Ion Diffusion in Portland Cement Mortars: Relationship to Sand Content and Critical Pore Diameter," Cem. and Conc. Res. 25, 790-802 (1995).

30

E.J. Garboczi and D.P. Bentz, "Computer Simulation of the Diffusivity of Cement-Based Materials," J. Mater. Sci. 27, 2083-2092 (1992).

31

A. Atkinson and A.K. Nickerson, J. Mater. Sci. 19, 3068 (1984).

32

R.T. Coverdale, B.J. Christensen, H.M. Jennings, T.O. Mason, D.P. Bentz, and E.J. Garboczi, "Interpretation of the impedance spectroscopy of cement paste via computer modelling I: Bulk conductivity and offset resistance," Journal of Materials Science 30, 712-719 (1995).

33

R.T. Coverdale, B.J. Christensen, T.O. Mason, H.M. Jennings, and E.J. Garboczi, "Interpretation of the impedance spectroscopy of cement paste via computer modelling II: Dielectric response," Journal of Materials Science 29, 4984-4992 (1994).

34

B.J. Christensen, T.O. Mason, H.M. Jennings, D.P. Bentz, and E.J. Garboczi, "Experimental and computer simulation results for the electrical conductivity of portland cement paste," in Advanced Cementitious Systems: Mechanisms and Properties, 245, 259-264 (Materials Research Society, Pittsburgh, 1992).

35

BJ. Christensen, Microstructure studies of hydrating portland cement-based materials using impedance spectroscopy, Ph.D. thesis, Northwestern University, Department of Materials Science and Engineering, 1993.

36

B.J. Christensen, T.O. Mason, R.T. Coverdale, H.M. Jennings, R.A. Olson, and E.J. Garboczi, Impedance spectroscopy and the electrical properties of hydrating cement-based materials: A review, Journal of the American Ceramic Society 77, 2789-2804 (1994).

37

D.P. Bentz and E.J. Garboczi, "Modelling the leaching of calcium hydroxide from cement paste: Effects on pore space percolation and diffusivity," Materials and Structures 25, 523-533 (1992).

38

E. Revertegat, C. Richet, and P. Gegout, Effect of pH on the durability of cement pastes, Cem. and Conc. Res. 22, 259-272 (1992).

39

P.K. Mehta and P.J.M. Monteiro, Concrete: Structure, Properties, and Materials (Prentice-Hall, Englewood Cliffs, New Jersey, 1993).

40

D.P. Bentz, E. Schlangen, and E.J. Garboczi, in Materials Science of Concrete IV, edited by J.P. Skalny and S. Mindess (American Ceramic Society, Westerville, OH, 1994), 155-200.

41

S. Diamond, S. Mindess, and J. Lovell, pp. C42 in Liasons Pater de Ciment Materiaux Associes, RILEM, Toulose, France, 1982.

42

D.P. Bentz, N.S. Martys, P.E. Stutzman, M.S. Levenson, E.J. Garboczi, J. Dunsmuir, and L.M. Schwartz, "X-Ray Microtomography of an ASTM C109 Mortar Exposed to Sulfate Attack," in Microstructure of Cement-Based Systems/Bonding and Interfaces in Cementitious Materials (Materials Research Society, Pittsburgh, 1995), 77-82.

43

J. Farran, Rev. Mater. Const. 490-491, 155-172 (1956).

44

J.C. Maso, in Proc. 7th Intl. Cong. on Chem. of Cement, Paris, 3-15 (1980).

45

Karen Scrivener, The Microstructure of Concrete, in Materials Science of Concrete I, ed. by Jan Skalny (American Ceramic Society, Westerville, 1990).

46

E.J. Garboczi and D.P. Bentz, "Digital simulation of the aggregate-cement paste interfacial zone in concrete," Journal of Materials Research 6, 196-201 (1991).

47

D.P. Bentz, E.J. Garboczi, and P.E. Stutzman, "Computer Modelling of the Interfacial Zone in Concrete," in Interfaces in Cementitious Composites, ed. by J. Maso (E and FN Spon, London, 1992), 107-116.

48

D.P. Bentz and E.J. Garboczi, "Simulation Studies of the Effects of Mineral Admixtures on the Cement Paste-Aggregate Interfacial Zone," American Concrete Institute Materials Journal 88, 518-529 (1991).

49

Z. Hashin, Analysis of Composite Materials: A Survey, Journal of Applied Mechanics 50, 481-505 (1983).

50

C.L. Page and V.T. Ngala, in Proceedings of Conference on Chloride Diffusivity in Concrete, RILEM, France (1995).

51

J. Ollivier, J. of Adv. Cement-Based Mater., in press (1996).

52

Y.F. Houst, H. Sadouki, and F.H. Wittmann, Influence of aggregate concentration on the diffusion of CO2 and O2, in Interfaces in Cementitious Composites, ed. by J. Maso (E and FN Spon, London, 1992), 279-288.

53

R.W. Zimmerman, M.S. King, and P.J. M. Monteiro, Cem. Con. Res. 16, 239 (1986).

54

A. Ulrik Nilsen and P.J.M. Monteiro, Concrete: A Three Phase Material, Cem. and Conc. Res. 23, 147-151 (1993).

55

M.D. Cohen, A. Goldman, and W.F. Chen, The role of silica fume in mortar: Transition zone versus bulk paste modification, Cem. and Conc. Res. 24, 95-98 (1994).

56

K.A. Snyder and J.R. Clifton, Measures of air void spacing, in Proceedings of the International Conference on Building Materials, Weimar, Germany, 155-157 (1994).

57

K.A. Snyder, J.R. Clifton, and L.I. Knab, Freeze-thaw susceptibility of high performance concrete, in Proceedings of the International Conference on Building Materials, Weimar, Germany, 139-142 (1994).

58

A.I. Rashed and R.B. Williamson, Journal of Materials Research 6, 2004-2012 (1991).

59

D.N. Winslow, M. Cohen, D.P. Bentz, K.A. Snyder, and E.J. Garboczi, "Percolation and porosity in mortars and concretes," Cem. and Conc. Res. 24, 25-37 (1994).

60

S. Torquato, J. Chem. Phys. 85, 6248 (1986).

61

E.J. Garboczi, D.P. Bentz, and L.M. Schwartz, "Modelling the influence of the interfacial zone on the D.C. electrical conductivity of mortar," Journal of Advanced Cement-Based Materials 2, 169-181 (1995).

62

D.P. Bentz, J.T.G. Hwang, C. Hagwood, E.J. Garboczi, K.A. Snyder, N. Buenfeld, and K.L. Scrivener, "Interfacial Zone Percolation in Concrete: Effects of Interfacial Zone Thickness and Aggregate Shape," in Microstructure of Cement-Based Systems/Bonding and Interfaces in Cementitious Materials (Materials Research Society, Pittsburgh, 1995), 437-442.

63

G. E. Pike and C. H. Seager, Phys. Rev. B 10, 1421 (1974).

64

A.L. Bug, S.A. Safran, G.S. Grest, and I. Webman, Phys. Rev. Letts. 55, 1896 (1985).

65

D. W. Cooper, Phys. Rev. A 38, 522 (1988).

66

L.M. Schwartz, E.J. Garboczi, and D.P. Bentz, "Interfacial transport in porous media: Application to D.C. electrical conductivity," Journal of Applied Physics 78, 5898-5908 (1995).

67

D. Winslow and D. Liu, Cem. and Conc. Res. 20, 227-234 (1990).

68

K.A. Snyder, D.N. Winslow, D.P. Bentz, and E.J. Garboczi, Effects of Interfacial Zone Percolation on Cement-Based Composite Transport Properties, in Advanced Cementitious Systems: Mechanisms and Properties, ed. by F.P. Glasser, G.J. McCarthy, J.F. Young, T.O. Mason, and P.L. Pratt (Materials Research Society, Pittsburgh, 1992), 265-270.

69

K.A. Snyder, D.P. Bentz, E.J. Garboczi, and D.N. Winslow, Interfacial zone percolation in cement-aggregate composites, in Interfaces in Cementitious Composites, ed. by J. Maso (E and FN Spon, London, 1992), 259-268.

70

D.N. Winslow and S. Diamond, ASTM J. of Materials 5, 564 (1970).

71

L.M. Schwartz and J.R. Banavar, Phys. Rev. B 39, 11965-11970 (1989).

72

I.C. Kim and S. Torquato, Phys. Rev. A 43, 3198 (1991).

73

D.C. Hong, H.E. Stanley, A. Conoglio, and A. Bunde, Phys. Rev. B 33, 4564 (1986).

74

E.J. Garboczi and D.P. Bentz, "The effect of the interfacial transition zone on concrete properties: The dilute limit," November, 1996 Amer. Soc. Civil Eng. 4th Materials Conference, Washington, DC.

75

R.E. De La Rue and C.W. Tobias, J. Electrochemical Soc. 106, 827 (1959).

76

S. Torquato, Appl. Mech. Rev. 44, 37 (1991).

77

Z. Hashin, J. Composite Mater. 2, 284 (1968).

78

McLaughlin, Int. J. Eng. Sci. 15 , 237 (1977).

79

ASTM Standard C-109, in ASTM Annual Book of Standards 04.01: Cement; Lime; Gypsum (ASTM, Philadelphia, 1995).

80

D.P. Bentz, D.A. Quenard, V. Baroghel-Bouny, E.J. Garboczi, and H.M. Jennings, "Modelling drying shrinkage of cement paste and mortar Part 1: Structural models from nanometers to millimeters," Materials and Structures 28, 450-458 (1995).

81

Baroghel-Bouny, V., PhD thesis, L'ecole Nationale des Ponts et Chaussees, France 1994.

82

D.R. Clarke, Interpenetrating Phase Composites, J. Am. Ceram. Soc. 75, 739-759 (1992).

83

D.P. Bentz, E.J. Garboczi, and E.S. Lagergren, "Multi-scale microstructural modelling of concrete diffusivity: Identification of significant variables," ASTM Cement and Aggregates, 20, 129-139 (1998).

84

E.J. Garboczi and D.P. Bentz, "Multi-scale analytical/numerical theory of the diffusivity of concrete," J. of Adv. Cem.-Based Mater., 8, 77-88 (1998).