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A methodology is proposed for the characterization of fire
resistive materials with respect to thermal performance models. Typically in
these models, materials are characterized by their densities, heat capacities,
thermal conductivities, and any enthalpies (of reaction or phase changes). For
true performance modeling, these thermophysical properties need to be determined
as a function of temperature for a wide temperature range from room temperature
to over 1000 ºC. Here, a combined experimental/theoretical/modeling approach is
proposed for providing these critical input parameters. Particularly, the
relationship between the three-dimensional microstructure of the fire resistive
materials and their thermal conductivities is highlighted.