Prediction of a Chloride Ion Penetration Profile for a Concrete

Please supply the following parameters (defaults provided)

Environmental Parameters

  Month     Ext. chloride      Temperature (oC)
         conc. (moles/liter)

January                

February               

March                  

April                  

May                    

June                   

July                   

August                 

September              

October                

November               

December               

Total duration of exposure days

Unexposed boundary condition is Constant at zero Reflecting boundary (no chloride escape)

Structural Design Parameters

Member thickness m

Depth of Reinforcement mm

Concrete Mixture Parameters

w/c ratio

Degree of hydration

Volume fraction of aggregate %

Air content %

Initial chloride concentration of concrete g chloride/g cement Guidance

Diffusion Coefficients (D)

Click here to view database of concrete diffusivities from literature.

Note that all diffusion coefficients are apparent diffusivity values, as we are modelling transport in the pore space of the concrete based on Fick's 2nd law.

Time dependent diffusion coefficient for bulk concrete takes the form of D=D_inf+D_i*t^-m

Be sure that you use values of m in the range (0,1).

Reference: Mangat and Molloy, Materials and Structures, Vol. 27, 338-346, 1994. Note- Mangat and Molloy found m values ranging from 0.44 to 0.86 and also that approximately:

m=2.5(w/c)-0.6

To have a constant D value with time, simply set D_inf to this desired value and D_i to zero

D_inf m*m/s at 25 C

D_i m*m/s

m

Curing time before exposure of concrete to chlorides days

The surface layer of the concrete may have a different (lower or higher) D value than the bulk concrete due to carbonation or poor curing practices. Input the surface layer D value relative to the bulk D value and the thickness of this layer. To bypass this feature, set the skin layer thickness to 0.0 or use D(surface concrete)/ D(bulk concrete)=1.0.

Ratio D (surface concrete)/D (bulk concrete)

Thickness of surface layer mm

Activation Energy for diffusion kJ/mole

Chloride Binding Parameters Guidance

Based on a Langmuir isotherm of the form:
  C(bound)=(alpha*C(free))/(1.+beta*C(free))

where C(bound) is in (mole Cl-)/kg cement and
C(free) is in (mole Cl-)/L

Alpha

Beta

Rate constant for binding s-1

Chloride Reaction Parameters Guidance

Assuming the formation of Freidel's salt from all of the 
C3A and C4AF initially available in the cement powder.

C4AF content of cement % on a mass basis

Rate constant for aluminate reactions with chloride s-1

New Feature (March 2006)

Allows application of a surface treatment at a specific time, beyond which further transfer of chlorides into/out of the top surface is prohibited.

Set this time to a time greater than the total exposure time to turn off this feature

Time at which surface treatment is applied days

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